n(Na)=0.69/23=0.03mol n(AlCl3)=0.1*0.5=0.05mol
Na----NaOH
1mol 1mol
0.03molx=0.03mol
AlCl3 + 4NaOH======NaAlO2 +3 NaCl +2H2O
1mol 4mol
0.05mol x=0.2mol
AlCl3 +3NaOH ====NaCl + Al(OH)3
3mol 78g
x=0.03mol 0.78g
所以还要NaOH的物质的量为:0.2-0.03=0.17mol
Na----------NaOH
23 1mol
x=3.91g 0.17mol
再投入3.91g Na可使沉淀恰好完全溶解
恰好完全溶解溶质就是 NaAlO2和 NaCl
n(Al)==0.5*0.1==0.05 mol n(Cl)==3*n(Al)==0.15 mol
已经加入n(Na)==0.69/23==0.03 mol
则还需Na为 0.05+0.15-0.03==0.17 mol 即 0.17*23==3.91 g