推荐回答(4个)
聚丙烯分子链基本为线性结构,加热软化点与熔点接近,熔体强度低、耐熔垂性差,限制了其在热成型、挤出涂布、发泡和吹塑等领域的应用,因此,提高聚丙烯熔体强度一直是聚丙烯新产品开发中的重要课题。提高聚丙烯熔体强度一般可以采用提高聚丙烯分子量及其分布和引入支链结构的办法,也可以采取在加工时与其他非晶或低结晶树脂、弹性体等共混。高熔体强度聚丙烯(HMSPP)就是指熔体强度对温度和熔体流动速率不太敏感的聚丙烯。
高熔体强度聚丙烯的研究虽然起自20世纪80年代末,但它的各种优异性能、合理的价格优势以及广泛的应用范围已经获得世界范围的认同,并有逐步取代传统的PS、ABS,向工程塑料发展的趋势,其开发利用前景广阔。
昊智高熔体强度聚丙烯(HMSPP)含有长支链结构,在拉伸过程中表现出应变硬化,具有很高的熔体强度,从而有利于防止在零剪切速率下,熔体的变形或者由重力作用引起的缺陷,可广泛应用于挤出发泡成型、EPP粒、注塑发泡成型、热成型、吹塑成型和挤出涂层等领域。
聚丙烯(PP)是目前世界上应用最为广泛 ,产量增长最快的树脂之一。与其他热塑性树脂相比 ,PP具有低密度、高熔点、来源广、价格低以及机械性能优越、化学稳定性好等特点 ,已经成为包装、轻工、建筑、电子、电器和汽车等行业不可缺少的基本原料。
普通商品聚丙烯,其分子量分布相对较窄 ,导致聚丙烯的软化点与熔点较接近 ,熔程较短。这在热成型加工中表现为当温度高于熔点后 ,熔体黏度急剧下降 ,熔融态下拉伸时不能出现应变硬化现象 ,进而导致聚合物的抗熔垂性能差 ,热成型制品壁厚不均 ,挤出涂覆、压延时边缘卷曲、收缩 ,挤出发泡时泡孔塌陷等问题。这一缺点极大地限制了聚丙烯的应用。高熔体强度聚丙烯 ( high melt strength PP ,HMSPP)就是针对以上不足而开发的一种新型聚丙烯材料。由HMSPP制得的制品具有良好的热稳定性和高温下尺寸稳定性 ,较高的韧性和拉伸强度 ,优异的微波适应性 ,良好的环境效应和易回收等特点。
改善了各种的成形性
挤出发泡特性
√ 形成均匀、微细的气泡。
√ 由于连续气泡率低,所以拥有卓越的二次成形性。
√制成的一次性餐盒,可微波加热、隔热保温,可回收
热成形性
√ 改善了垂伸的特性。
√ 因为有着良好的延伸性能,所以大型复杂的形状也可以轻松成形。
薄膜成形
√ 对应CPP高速成形性(改善缩幅,牵伸共振)。
√ 改善风冷吹膜时的膜泡稳定性。
注塑成型
√注塑成型后的制品密度在0.3-0.9之间,质量轻,不大影响其性能。
√成型周期缩短30%-50%
√锁模力降低30%-70%
√能耗降低50%
超临界物理发泡
√可用于超临界发泡制备0.035g/cm3的EPP珠粒
√制品耐热、耐化学品、耐油和隔热
√优异的抗震、吸能性能及形变后恢复率高
√可用于超临界发泡,连续生产发泡倍率3-20倍的板材或片材。
科亚隆高熔体强度PP,抗熔垂,应变硬化,泡孔均匀致密,产品可回收利用。
聚赛龙高熔体强度聚丙烯具有较高的熔体强度,其拉伸粘度随剪切应力和时间的增加而增加,应变硬化行为明显,可以在热成型、吹塑成膜、挤出涂覆、挤出发泡等方面推广应用。尤其在PP挤出发泡材料方面,效果显著,解决了普通聚丙烯难以发泡成型加工的问题。
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