尼龙+13%的玻纤,收缩率是多少?

2025-03-11 02:54:51
推荐回答(2个)
回答(1):

次膦酸盐阻燃玻纤增强尼龙66

2005年1月9日14时57分 慧聪网塑料行业

阻燃GPPA在电子电器工业中具有广泛的用途,且特别适用于制造在高电压下使用的注塑电子元器件。目前,溴代聚苯乙烯(BPS)及红磷在阻燃GPPA制品中应用较多。但是BPS作为卤系阻燃剂,用量较多,阻燃产品的电绝缘性能也欠缺,这两种阻燃剂阻燃GPPA(玻纤含量25%-30%)的漏流经迹指数CTI值约为400V(未阻燃产品的CTI值为600V)以红磷阻燃GPPA时,阻燃剂用量最少,但是红磷的颜色限制了它的使用。当然,非卤系阻燃剂还有及聚磷酸三聚氰胺(MPP),不过这两种阻燃剂用量过多,影响制品的机械性能,而MPP阻燃GPPA时抗冲击强度不能令人满意。

德国Clariant公司开发了两种次膦酸盐基阻燃剂,牌号为Exolit OP1311和Exolit OP1312M1,现已经中试生产,工业生产已经在2004年年末开始,这两种磷系阻燃剂都是以固相阻燃机理发挥作用,促进成碳,强化碳层结构,且能与氮产生协效作用,特别适用于GPPA6和GPPA66。Exolit OP1312M1的热稳定性优于Exolit OP1311,后者主要用于阻燃GPPA6,而前者主要用于GPPA66。这类阻燃产品密度较低,阻燃剂用量也比较少,制品机械性能较好,色调选择自由,烟密度较低,CTI值较高,在电子电气工业中很有应用前景。

1, 阻燃GPPA66的制备
GRPA66系以27-44D同向双螺杆挤出机造粒,造粒时,PA由主进料口加入,阻燃剂由18D的第一侧进料口加入,玻纤由30D的第二侧进料口加入,在15D常压脱气,40D减压脱气,进料总量为20KG/min,螺杆转速为250r/min,混炼温度为250~280℃。所得料粒在80下干燥至水分含量小于0.1%。注塑测试样条。

2, 阻燃GRPA66的配方
为了比较次膦酸盐与其它GRPA66常用阻燃剂的功效,分别以BPS 红磷(RP)及 Exolit OP1312M1阻燃GRPA66,并同时测定了这几种阻燃GRPA66得多项性能,所用阻燃材料的配方见表1:
表1 三种阻燃GRPA66的配方
材料
配方% GRPA66 BPS阻燃 红磷阻燃 ExolitOP1312M1阻燃
PA66 70 43.6 56 52
玻纤 30 30 30 30
BPS 20
Sb2O3母粒 6.0
红磷母粒 14
ExolitOP1312M1 18
PTFE 0.4

1, PA66为巴斯夫的DurethanA30.
2, 玻纤为法国Vetrotex公司的VetrotexEC104.5MM983
3, BPS为比利时Albemarle公司的Saytex HP-7010
4, Sb2O3母粒以PA66为载体,Sb2O3含量为80%,此母粒由比利时Camprme公司 生产,牌号为Antiox PA2617
5, 红磷母粒以PA66为载体,P含量为50%,此母粒由法国Clariant公司生产,牌号Exolit RP695
6, ExolitOP1312M1由法国Clariant生产。

3 阻燃GRPA66的物理机械性能及阻燃性
实测的有关结果示于表2。测定的标准如下:熔体指数 ISO 1133;抗拉强度、抗拉模量及断裂伸长率 ISO 527-2;抗冲强度 ISO 179/LEV。

表2 阻燃GRPA66的物理机械性能及阻燃性
材料
性能 GRPA66 BPS阻燃 RP母粒阻燃 阻燃
熔体指数/cm3 10 3 4 7
抗拉强度/MPa 177 164 174 132
抗拉模量/MPa 9.6 12.3 11 9.9
断裂伸长率/% 3.7 2.7 3.2 2.8
抗冲强度/KJ.m -2 79 64 78 64

回答(2):

0.6

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