解:如图所示,∵此正多边形是正六边形,∴∠ABC=120°,连接AC,过B作BD⊥AC于点D,∵AC=2,∴AD=1,∠ABD= 1 2 ∠ABC=60°,∴AB= AD sin∠ABD = 1 3 2 = 2 3 3 .故答案为: 2 3 3 .