(1)有A、B、C、D、E五种短周期元素,它们的原子序数依次增大.已知:A和C、B和D分别位于同主族,且B、D

2025-03-26 07:27:32
推荐回答(1个)
回答(1):

(1)A、B、C、D、E五种短周期元素,它们的原子序数依次增大,A和C、B和D分别位于同主族,结合原子序数可知,B一定处于第二周期、D处于第三周期,而C的原子序数大于B,则B、C一定不能处于同周期,故C处于第三周期,E原子序数大于D,E在同周期元素中原子半径最小,所以E是Cl元素;故B、D的质子数之和最大为8+16=24,则A、C的质子数之和最大为12,由于C处于第三周期,故A为H、C为Na、B为O、D为S,则:
①H2O和H2S都是氢化物,其固体都属于分子晶体,分子晶体中物质的沸点与其相对分子质量成正比,但水中含有氢键,硫化氢中不含氢键,所以二者的沸点较高者是H2O,
故答案为:H2O;水中含有氢键,硫化氢中不含氢键;
②C为Na,处于周期表中第三周期第ⅠA族;同周期随原子序数增大第一电离能呈增大趋势,故第一电离能Na<S,
故答案为:第三周期第ⅠA族;小于;
原子个数相等价电子数相等的微粒是等电子体,与H3O+互为等电子体的分子为:NH3
故答案为:NH3
③E是Cl元素,其原子核外有17个电子,根据构造原理知,Cl原子的电子排布式为1s22s22p63s23p5;同周期随原子序数增大,电负性增大,故电负性Cl>D,
故答案为:1s22s22p63s23p5 ;大;
(2)二氧化硫具有漂白性,可以使品红溶液褪色;二氧化硫与碱反应生成盐与水,说明其为酸性氧化物,故可以用滴加酚酞的氢氧化钠溶液验证;
①瓶中集满SO2气体,进入瓶中的品红溶液褪为无色,说明二氧化硫具有漂白性,
故答案为:漂白;
②二氧化硫与碱反应生成盐与水,可以用滴加酚酞的氢氧化钠溶液验证,溶液红色褪去或变浅,说明其为酸性氧化物,
故答案为:滴加酚酞的氢氧化钠溶液;溶液红色褪去或变浅;
③溴与二氧化硫在水中反应生成硫酸与HBr,反应方程式为Br2+SO2+2H2O═H2SO4+2HBr,
故答案为:Br2+SO2+2H2O═H2SO4+2HBr;
(3)燃料电池中,负极上投放的是燃料,负极上燃料失电子发生氧化反应,N2H4在碱性环境下生成氮气与水,负极的反应式为:N2H4+4OH--4e-═4H2O+N2↑,
反应方程式为:N2H4+2H2O2═N2+4H2O,1g液态肼放出20.05kJ的热量,则1mol液态肼放出的热量为20.05kJ×

1mol×32g/mol
1g
=641.6kJ,所以反应的热化学方程式为:N2H4(g)+2H2O2(l)═N2(g)+4H2O(g),△H=-641.6kJ/mol,
故答案为:N2H4+4OH--4e-═4H2O+N2↑;N2H4(g)+2H2O2(l)═N2(g)+4H2O(g),△H=-641.6kJ/mol.

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